Dynamics of photogenerated holes in nanocrystalline α-Fe2O3 electrodes for water oxidation probed by transient absorption spectroscopy.
نویسندگان
چکیده
Transient absorption spectroscopy on the μs-s time scale is used to monitor the yield and decay dynamics of photogenerated holes in nanocrystalline hematite photoanodes. In the absence of a positive applied bias, these holes are observed to undergo rapid electron-hole recombination. The application of a positive bias results in the generation of long-lived (3 ± 1 s lifetime) photoholes.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 2 شماره
صفحات -
تاریخ انتشار 2011